(4)寫出A在加熱條件下與溶液反應的化學方程式 查看更多

 

題目列表(包括答案和解析)

第四部分:寫作(共三節(jié),滿分45分)

第一節(jié):課文回放:根據(jù)課文內容將下面短文補充完整,單詞的首字母已經(jīng)為你寫出(注意:在答卷上要寫出所填單詞的首字母及其它字母的正確形式,否則不給分)。(15分)

☆A  (Unit 1   Book 4  Women of Achievements) ★

Jane Goodall, who had intended to work with animals in their own environment since her (66) c_________, went to (67) A________ and devoted herself to (68) _________ (study) the behavior of chimps. It was tough but she considered it as a (69) w_________ career. Through her study, we learned much more about chimps. She argues that the life of these animals should be (70) r_________ and that they should be left in the wild and not used for (71) e_________ or advertisements. Besides, she was very (72) c__________ of these animals. Now, she has achieved everything she wanted to do, which inspired those who want to cheer the achievements of women.

☆B  (Unit 2  Book 4  Working the Land) ★

Yuan Longping, a man who graduated from Southwest Agricultural College in 1953 and now works the land, does his research and grows hybrid rice. He is an agricultural (73) p_________ to have a high output of rice without (74) e_________ the area of fields. He devotes his whole life to finding ways to increase the rice output, to (75) f_________ the Chinese and the world people. He is (76) c_________ his knowledge so that more farmers can be free from (77) h_______ and satisfied with their lives. Yuan cares little about his money and fame, devoting a great deal of time and money helping others doing agricultural research. He wishes for more cheap rice for all the people. Yuan Longping is a great (78) p_________.

☆B  (Unit 3  Book 4  A Taste of English Humour) ★

Chaplin’s parents were poor music hall performers. It was (79) a__________ that Chaplin was brought up successfully when he was very young. Unfortunately, his parents died, leaving the family even worse off. Chaplin could act the fool doing ordinary everyday tasks. Nobody was ever bored watching him, for he made everything entertaining.

He became known (80) t__________ the world later. He wrote, directed and produced the films he starred in. In 1972, he was given a special Oscar for his outstanding work in films. He spent his last years in Switzerland, where he was buried in 1977.

 

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第四部分:寫作(共三節(jié),滿分45分)
第一節(jié):課文回放:根據(jù)課文內容將下面短文補充完整,單詞的首字母已經(jīng)為你寫出(注意:在答卷上要寫出所填單詞的首字母及其它字母的正確形式,否則不給分)。(15分)
☆A  (Unit 1   Book 4  Women of Achievements) ★
Jane Goodall, who had intended to work with animals in their own environment since her (66) c_________, went to (67) A________ and devoted herself to (68) _________ (study) the behavior of chimps. It was tough but she considered it as a (69) w_________ career. Through her study, we learned much more about chimps. She argues that the life of these animals should be (70) r_________ and that they should be left in the wild and not used for (71) e_________ or advertisements. Besides, she was very (72) c__________ of these animals. Now, she has achieved everything she wanted to do, which inspired those who want to cheer the achievements of women.
☆B  (Unit 2  Book 4  Working the Land) ★
Yuan Longping, a man who graduated from Southwest Agricultural College in 1953 and now works the land, does his research and grows hybrid rice. He is an agricultural (73) p_________ to have a high output of rice without (74) e_________ the area of fields. He devotes his whole life to finding ways to increase the rice output, to (75) f_________ the Chinese and the world people. He is (76) c_________ his knowledge so that more farmers can be free from (77) h_______ and satisfied with their lives. Yuan cares little about his money and fame, devoting a great deal of time and money helping others doing agricultural research. He wishes for more cheap rice for all the people. Yuan Longping is a great (78) p_________.
☆B  (Unit 3  Book 4  A Taste of English Humour) ★
Chaplin’s parents were poor music hall performers. It was (79) a__________ that Chaplin was brought up successfully when he was very young. Unfortunately, his parents died, leaving the family even worse off. Chaplin could act the fool doing ordinary everyday tasks. Nobody was ever bored watching him, for he made everything entertaining.
He became known (80) t__________ the world later. He wrote, directed and produced the films he starred in. In 1972, he was given a special Oscar for his outstanding work in films. He spent his last years in Switzerland, where he was buried in 1977.

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單詞填空:根據(jù)下列句子句意及漢語或英語提示,寫出所缺單詞或使用括號中詞語的正確形式填空。(每空一詞)(共15小題;每小題1分,滿分15分)

1.       We all have some ___________(缺點) and we should improve ourselves.

2.       Does environment___________(決定)one’s character?

3.       She refused to give the taxi___________(費用) because of the delay.

4.       Do you have any ______________(保險)on your car?

5.       What’s your _____________(態(tài)度) to this idea? Is it good or bad?

6.       Since Li Ming _________________ here, he has got along well with his neighbours. (settle)

(李明在這里定居后,和鄰居們相處得很好。)

7.       While_________( walk) the dog, you were careless and it got loose and was hit by a car.

你在遛狗的時候,你不小心讓狗松開了,結果被車撞了。

8.       When people use words and ____________(express) different from the “standard language”,it is called a dialect.(當人們用不同于“標準語言”的詞語和表達時,那就叫做方言。)

9.       Earthquakes are one of the most deadly natural________(災難) in the world.

10.    More ________(避身處)for the homeless should be built in some big cities.

11.   _________(百萬)of people watched the exciting football game , according to CCTV-5.

12.   As _______(照常,慣常), it rained on my birthday.

13.   ________they looked nearly everything was destroyed.

(人們無論朝哪里看,哪里的一切都幾乎被毀了。)

14.   we can __________(hard) wait to see them!(我們迫不及待地想要見到他們。)

15.   People began to wonder how long the disaster would____________(持續(xù))。(人們開始納悶,這場災難還會持續(xù)多久)

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單詞拼寫
     根據(jù)下列各句句意和空白之后的漢語提示詞,在橫線上寫出對應單詞的正確、完整形式,
每空只寫一詞

1. An active attitude towards life can people deal with whatever ________ (挑戰(zhàn))they may come
    across in daily life.
2. A marriage has been _____________(籌備;安排) between Mr. Brown and Miss. White.
3. I'm surprised to know you got an unfavorable ________________(印象)of him.
4. I regret that a ___________(在前的) appointment prevents me from accepting your kind invitation.
5. Are you hoping to ___________(申請)for higher education courses in the UK.
6. He is tired and can't _____________(集中) on what the teacher is saying.
7. Just now the nurse ____________(通知) me that visiting hours were over.
8. What is one man's meat is another man's ______________(毒藥).
9. It is because that I always enjoy my life and I have an _____________(樂觀的) heart .
10. In the long run it's better to try to avoid that ______________(瞬間的;立刻的) satisfaction.

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第四部分:寫作(共三節(jié),滿分45分)

第一節(jié):課文回放:根據(jù)課文內容將下面短文補充完整,單詞的首字母已經(jīng)為你寫出(注意:在答卷上要寫出所填單詞的首字母及其它字母的正確形式,否則不給分)。

☆A  (Unit 1   Book 4  Women of Achievements) ★

Jane Goodall, who had intended to work with animals in their own environment since her (66) c_________, went to (67) A________ and devoted herself to (68) _________ (study) the behavior of chimps. It was tough but she considered it as a (69) w_________ career. Through her study, we learned much more about chimps. She argues that the life of these animals should be (70) r_________ and that they should be left in the wild and not used for (71) e_________ or advertisements. Besides, she was very (72) c__________ of these animals. Now, she has achieved everything she wanted to do, which inspired those who want to cheer the achievements of women.

☆B  (Unit 2  Book 4  Working the Land) ★

Yuan Longping, a man who graduated from Southwest Agricultural College in 1953 and now works the land, does his research and grows hybrid rice. He is an agricultural (73) p_________ to have a high output of rice without (74) e_________ the area of fields. He devotes his whole life to finding ways to increase the rice output, to (75) f_________ the Chinese and the world people. He is (76) c_________ his knowledge so that more farmers can be free from (77) h_______ and satisfied with their lives. Yuan cares little about his money and fame, devoting a great deal of time and money helping others doing agricultural research. He wishes for more cheap rice for all the people. Yuan Longping is a great (78) p_________.

   ☆B  (Unit 3  Book 4  A Taste of English Humour) ★

Chaplin’s parents were poor music hall performers. It was (79) a__________ that Chaplin was brought up successfully when he was very young. Unfortunately, his parents died, leaving the family even worse off. Chaplin could act the fool doing ordinary everyday tasks. Nobody was ever bored watching him, for he made everything entertaining.

   He became known (80) t__________ the world later. He wrote, directed and produced the films he starred in. In 1972, he was given a special Oscar for his outstanding work in films. He spent his last years in Switzerland, where he was buried in 1977.

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1.D【解析】β-珠蛋白DNA探針、RNA聚合酶結合位點、大腸桿菌質粒的化學本質都是DNA;胰島素是蛋白質;HIV的遺傳物質是RNA;生長素是吲哚乙酸;2,4-D是一種生長素類似物。

2.D【解析】作物“燒心”是由于缺乏如鐵、鈣等在細胞中以穩(wěn)定化合物形式存在的礦質元素,有別于因缺水而造成的“燒苗”。

3.B【解析】疫苗的作用是在機體不患病的情況下發(fā)生免疫反應,產(chǎn)生的抗體與抗原結合,發(fā)揮免疫效應;流感病毒的遺傳物質是單鏈的RNA,其結構穩(wěn)定性不如天花病毒的雙鏈DNA,容易發(fā)生變異,所以流感疫苗的研究的難度較天花疫苗研究的難度大很多;正是由于流感病毒極易發(fā)生變異,所以某種特定的單克隆抗體不一定對其它的抗原起作用。

4.C【解析】生態(tài)系統(tǒng)的成分除生產(chǎn)者、消費者和分解者外,還包括了非生物的物質和能量;生物圈的自給自足表現(xiàn)在物質上,能量來源于太陽能;草原上的牛和羊同屬于第二營養(yǎng)級,共獲得生產(chǎn)者固定太陽能的10%~20%。

5.B【解析】考查分泌蛋白的形成和分泌過程這一知識點和圖形分析能力。蛋白質分泌以細胞膜的外排方式實現(xiàn),所經(jīng)過的膜結構順序為:內質網(wǎng)→高爾基體→細胞膜,所以結果是:內質網(wǎng)面積減小,高爾基體膜面積不變,細胞膜面積增加。

6.B 【解析】有機分子的特點一般滿足C四鍵、H一鍵、N三鍵原則,三聚氰胺分子中含有3個-NH2,則其余3個C、3個N形成一個六元環(huán),故三聚氰胺的結構簡式為。。根據(jù)三聚氰胺的結構簡式,該物質不是高聚物,也不是氨基酸,但分子中含有不飽和鍵,在一定條件下能發(fā)生加成反應。六元環(huán)不變且除自身外的三聚氰胺的異構體有3種。

7.B   【解析】選項A,Na2O2中含有的陽離子為Na,陰離子為O22?,0.1mol  Na218O2中含有的陰陽離子總數(shù)為0.3NA。選項B,C2H4、C3H6的化學式均為CH2,1.4g二者含有的C原子數(shù)的物質的量=1.4g/14g?mol-1=0.1mol,即0.1NA。選項C,0.1mol Cl2參與反應電子轉移0.1mol。選項D,D2O為10電子微粒,18g D2O物質的量小于1mol,含有的電子數(shù)也小于NA

8.A 【解析】選項A,ClO具有氧化性,SO2具有還原性,SO2被氧化為SO42?,ClO被還原為Cl?,正確。選項B,加入少許H時,CO32?優(yōu)先與H結合生成HCO3?。選項C,離子方程式兩邊電荷不守恒。選項D,Mg2能與電解產(chǎn)生的OH?結合生成難溶性Mg(OH)2沉淀:Mg2 + 2Cl? + 2H2O=Mg(OH)2↓+ H2↑+ Cl2↑。

9. B 【解析】加入稀H2SO4出現(xiàn)白色混濁說明一定存在Ba2,因SO32?、CO32?能與Ba2結合生成難溶物BaSO3、BaCO3,所以原溶液中不存在SO32?、CO32?。由于溶液呈電中性,剩下的一種HCO3?,一定存在。無法判斷是否含有K,所以原溶液中一定含有Ba2、HCO3?,可能含有K。溶質可能是Ba(HCO3)2或Ba(HCO3)2和KHCO3

10.D 【解析】根據(jù)題設條件可推知A為NH4,B為OH?,C為NH3,D為H2O。NH3能與H2O反應生成NH3?H2O。NH4為離子,不是分子,所以NH4不是非極性分子。選項D,固態(tài)H2O分子間存在氫鍵,其熔沸點高于固態(tài)H2S,與H-O和H-S鍵強弱無關。NH4Cl ,NH4水解溶液的pH<7。

11.C【解析】分析反應①②中各元素的價態(tài)變化可知,反應①中,SO2為還原劑,F(xiàn)e3為氧化劑,且還原性:SO2>Fe2,氧化性:Fe3>SO42?。反應②中,F(xiàn)e2為還原劑,Cr2O72?為氧化劑,且還原性:Fe2>Cr3+ ,氧化性:Cr2O72? > Fe3。由此可見選項A、B錯誤。選項C,由于Cr2O72?具有氧化性,Na2SO3具有還原性,故Cr2O72? 能將Na2SO3氧化成Na2SO4。選項D,反應①中Fe2(SO4)3為氧化劑,反應②中Fe2(SO4)3為氧化產(chǎn)物。

12.C【解析】選項A,NaHS、Na2S溶液又因為有HS?、S2?的水解,使其溶液呈堿性,但S2?的水解能力大于HS?,故溶液的pH值:③>②。H2S溶液呈酸性,H2S和NaHS混合液中,由于HS?抑制的H2S的電離,故溶液的pH:④>①,4種溶液pH大小順序為:③>②>④>①。選項B,由于HS?抑制H2S的電離,所以H2S溶液中的c(H2S)小于H2S和Na2S混合液中的c(H2S)。選項C,c(Na)=0.1mol?L-1,根據(jù)物料守恒有:c(H2S) + c(HS?) + c(S2?)=0.2mol?L-1,故2c(Na)=c(H2S) + c(HS?) + c(S2?)。選項D,根據(jù)電荷守恒有:c(H) + c(Na)=c(OH?) + c(HS?) +2 c(S2?)。

13.B 【解析】設達平衡時生成SO3(g)物質的量為2x ,則剩余SO2(g)的物質的量為(3-2x),O2(g)(2-x),混合氣體總的物質的量為(5-x),根據(jù)阿伏伽德羅定律有5/(5-x)=1/0.9,解得x=0.5mol,再結合熱化學方程式可知,放出的熱量為196.6kJ/2=98.3kJ。選項B,起始物質的量改為 4mol SO2 、 3 mol O2 、2SO3 (g) 相當于加入6mol SO2、4mol O2,n(SO2)/n(O2)=3/2,故與第一次平衡是等效平衡,兩次平衡中SO2的轉化率、SO3的體積分數(shù)相等,故選項B正確,C錯誤。選項D,題目沒有告訴達平衡時的時間,無法計算反應速率。

14.AD【解析】由狀態(tài)方程知溫度升高而壓強增大體積必增大,故狀態(tài)I時氣體的密度比狀態(tài)II時氣體的密度大,A正確,平衡態(tài)II的溫度比狀態(tài)I高,故狀態(tài)I時分子的平均動能比狀態(tài)II時分子的平均動能小,B錯誤,由熱力學第一定律知從狀態(tài)I到狀態(tài)II過程中溫度升高內能變大,體積增大對外界做功,氣體要從外界吸熱,故C錯,D正確,故選AD。

15.答案:BD【解析】:在同一介質中紅光傳播速度最大,從AB面射入到BC面射出,紅光用的時間最短,故選項A錯.由于玻璃對紅光折射率最小,對紫光的折射率最大,即紫光的偏折本領最大,所以彩色光帶右邊緣的色光為紅光,左邊緣的色光為紫光,且紫光的頻率比紅光的要高,當紅光能讓某金屬板發(fā)生光電效應,紫光也一定能夠,故選項B正確.在同樣條件下做雙縫干涉實驗,波長越長,相鄰干涉條紋間距越大,而彩色光帶左邊緣的色光是紫光,其波長最短,故選項C錯.對玻璃而言,在七色光中,紅光的臨界角最大,當∠MNB逐漸變小時,射到AC面上的光的入射角變小,且紅光入射角小得更多,故紅光最先從從AC面透出,所以選項D正確.

16、答案 D 【解析】 燒斷細線后,無論是彈簧將A+BC彈開過程,還是AB分離后,系統(tǒng)始終動量守恒、機械能守恒;彈簧將A+BC彈開過程,A+BC動量大小相等,動能跟質量成反比,因此A+B的總動能是E/3,其中A的動能是E/6;當時C的動能是2E/3;前3個選項都錯,可判定D正確。證明:AB分離時,B+C的總動能是5E/6,B、C共速時彈性勢能最大,當時AB+C動量大小相等,動能跟質量成反比,因此B+C的動能是E/12,該過程B+C的動能損失就是此時的彈性勢能,因此Ep=5E/6- E/12=3E/4。

17.答案:ACD【解析】:根據(jù)波的傳播方向,可以判斷b質點此時刻振動方向沿y軸負方向,離開平衡位置,速度正在變小,A對;由圖象可知該波的波長是4m,根據(jù)發(fā)生明顯衍射現(xiàn)象的條件判斷D正確;根據(jù),由波干涉條件知C正確;經(jīng)過0.01s即半個周期,任何質點通過的路程都是2個振幅,即0.4m,B錯誤.

18.C【解析】從圖(甲)到圖(乙)的過程中,根據(jù)動能定理有:,所以;從拋出后到落地,根據(jù)動能定理得:,代入上式可得:

19.答案: BC 【解析】此模型為類雙星模型,兩電荷做圓周運動的角速度相等;兩個電荷之間的庫侖力充當各自做圓周運動的向心力,所以向心力大小相等,A錯,B對.由知,線速度大小與質量成反比,運動半徑與質量成反比,C對,D錯.

20.答案:ABD 【解析】天然放射性元素的半衰期與溫度改變無關。根據(jù)質能方程計算可知D答案正確。

21.答案:.D  【解析】地球同步衛(wèi)星是指與地球自轉同步的人造衛(wèi)星,它的周期是24小時,它的軌道平面只能在赤道,軌道也是固定的,但并不是說同一赤道平面內的、或是周期與地球自轉周期相等的就都是同步衛(wèi)星,故A、C是錯的、D是正確的;同步衛(wèi)星做圓周運動時,內部的儀器是處于失重狀態(tài)而不是超重狀態(tài),B錯

22.答案.(1)(g+a)× (OM-ON)=(g-a)× OP    (4分)

【解析】利用紙帶分析得m1帶動m2的加速度為a ,又由牛頓第二定律得a=解得

3000;(2分)

(1分);乙圖中電流表的示數(shù)太小,誤差太大丙圖中R的阻值與電壓表阻值接近,誤差小。(3分)。

⑶實物圖連接如右圖所示:(4分)

⑷實驗步驟:

閉合K1.再閉合K,讀得電壓表示數(shù)U;再斷開K,讀得電壓表示數(shù)U.(2分) ②RV。(2分)

23.【解析】:(1)負電……(2分)∵mg =E×……(5分)

E=4(r+R)dmg/Rq…………(2分)

(2)mg+q v0B=……………(5分)    ∴v0=mg/qB…………(2分)

24.【解析】:(1)ab通過最大電流時,受力分析如圖甲,此時靜摩擦力最大,,方向沿斜面向下,由平衡條件得:

水平:

(3分)

豎直:(3分)

以上兩式聯(lián)立得出

(3分)

(2)通以最小電流時,ab受力分析如圖乙,此時ab受靜摩擦力,方向沿斜面向上,與(1)類似,由平衡條件得:(3分)

(3)當ab中電流最小時,變阻器阻值為:(3分)

當ab中電流最強時,變阻器阻值為:,(2分 )

為保持ab靜止,R的調節(jié)范圍為0.91~10.(1分)

25.【解析】:(1)設A物塊碰撞B物塊前后的速度分別為v1和v2,碰撞過程中動量守恒,

  代入數(shù)據(jù)得:        (4分)

(2)設A、B兩物塊碰撞前后兩物塊組成的系統(tǒng)的機械能分別為E1和E2,機械能的損失為,根據(jù)能的轉化和守恒定律:   

     %     (4分)

(3)設物塊A的初速度為v0,輪胎與冰面的動摩擦因數(shù)為µ,A物塊與B物塊碰撞前,根據(jù)動能定理:                 (3分)

碰后兩物塊共同滑動過程中根據(jù)動能定理:

         (3分)

、  及(1)、(2)得:    (2分)

設在冰面上A物塊距離B物塊為L′時,A物塊與B物塊不相撞,

則:                             (4分)

26.(15分)(1)(1)KNO3 (2分)CuSO4(2分)

(2) Na2CO3  (2分)

(3)Al3 + 3OH?=Al(OH)3↓(3分) Al(OH)3 + OH?=AlO2? + 2H2O (3分)

(4) Al3 + 3H2O Al(OH)3(膠體)+ 3H (3分)

【解析】根據(jù)實驗①可知,D中含有Cu2;根據(jù)實驗②可知C中含有Al3,E可能是KOH或NaOH,再根據(jù)③,只有B、C中含有K,故E為NaOH。根據(jù)實驗③A中含有HCO3?,故A為NaHCO3,C、D中含有SO42?,故D為CuSO4,C為KAl(SO4)2。

最后可判定B為KNO3。等物質的量的NaHCO3與NaOH反應生成Na2CO3和H2O。 NaOH溶液加入到KAl(SO4)2溶液中,首先是Al3與OH?反應生成Al(OH)3,Al(OH)3沉淀又溶解在過量的NaOH溶液中:Al3 + 3OH?=Al(OH)3↓,Al(OH)3 + OH?=AlO2? + 2H2O。KAl(SO4)2中的Al3水解生成具有吸附作用的Al(OH)3膠體而凈水。

27.(14分)(1)Na2CO3 +HCl=NaHCO3 + NaCl    (3分)

(2)Cl2 + 2OH?=Cl? + ClO? + H2O (3分)

(3)①Na2O或Na2O2  (4分,每空各2分)②Na或NaOH (4分,每空各2分)

【解析】(1)根據(jù)題設條件可知,B為鹽酸,C為CO2,D為H2O,E為NaCl。

(2)根據(jù)題設條件可知B為濃鹽酸,C為Cl2。

(3)若C為O2,D、E的焰色反應均為黃色,D、E中含有Na,含有Na的能產(chǎn)生O2的固體為Na2O2,E能與鹽酸反應生成的氣體能使澄清石灰水變混濁,該氣體為CO2,B、E可相互轉化,故可推知B溶液為NaHCO3溶液,E為Na2CO3溶液,D為NaOH溶液。Na2O2與NaHCO3溶液反應可分解為:2Na2O2 + 2H2O=4NaOH + O2↑,NaHCO3 + NaOH=Na2CO3 + H2O。amol NaHCO3→a mol Na2CO3,只要增加a mol Na,同時用OH? 將HCO3?轉化為CO32? ,所加物質所產(chǎn)生的Na和OH?的物質的量相等,才能不產(chǎn)生雜質,故X為Na2O或Na2O2,Y為Na或NaOH。

28.(16分)(1)B(2分)  銅與HNO3反應前,應排凈裝置內的空氣,防止NO與O2發(fā)生反應 (2分)

(2)將C中的溶液加適量水稀釋(2分)

(3)③④⑤⑨ (3分)

(4)第二,打開a,通足量N2,排凈裝置中的空氣(2分)

(5)向下移動乙管,使甲、乙兩管液面在同一水平面上(2分)
(6)(V-11.2n)/33.6n (3分)

【解析】根據(jù)實驗目的,要求得m值,需測定出Cu與HNO3反應生成的NO2和NO的物質的量,為此需將產(chǎn)生的氣體首先通入裝置C中,H2O吸收NO2生成NO和HNO3,用裝置E測定出NO的體積,如果裝置中有空氣,空氣中的O2會將NO氧化成NO2導致實驗誤差,裝置B通入N2能將裝置中空氣趕走,防止NO被氧化,為此需要的裝置為B、C、E,裝置接口連接順序為③④⑤⑨。由于濃HNO3具有強氧化性,能將指示劑氧化而影響實驗,可加水稀釋降低其氧化性,而溶質HNO3的量不變,便于觀察指示劑顏色變化。用裝置E測定NO的體積時,如甲的液面高于乙的液面,測出的NO體積偏小,如甲的液面低于乙的液面,測出的NO體積偏大,故應向下移動乙管,使甲、乙兩管液面在同一水平面上,從而減少誤差。根據(jù)反應:3NO2 + 2H2O=2HNO3 + NO,混合氣體中含有NO21.5nmol,NO總的物質的量為V/22.4mol,其中屬于Cu與HNO3反應生成的NO為(V/22.4-n/2)mol,故M=(V/22.4-n/2):1.5n=(V-11.2n)/33.6n。

29.(15分)(1)取代(或水解)、中和反應 (2分) (2)HCOOCH3  (2分) HOCH2CHO (2分)

(3)(2分)

  (4)+ 3NaOH+ CH3COONa + 2H2O (3分)

(5) (2分) (2分)

 

【解析】A的分子式為C9H8O4,A能與醇發(fā)生酯化反應,說明A中含有-COOH,且A在NaOH溶液中發(fā)生水解生成CH3COONa,說明A中酯的官能團,該官能團與-COOH處于苯環(huán)上的鄰位,再結合A的分子式推知A的結構簡式為,B為,由于H2CO3的酸性大于酚而小于羧酸,故在溶液中通入CO2時,只有酚的鈉鹽反應生成D()和NaHCO3。CH3COONa與H反應生成E(CH3COOH)。CH3COOH的同分異構體中R中含有-CHO和-OH:HOCH2CHO,Q中含有-CHO而沒有-OH:HCOOCH3。對照結構可知,首先用與酚羥基反應,然后再用酸性KMnO4氧化-CH3為-COOH即可得到A。

30.【解析】(1)新陳代謝是生物最本質的特征。(2)人體內水的來源包括:飲水、食物中的水、代謝產(chǎn)生的水,人體代謝產(chǎn)生水的途徑有:核糖體上的氨基酸脫水縮合、線粒體中的有氧呼吸等。(3)異化作用類型包括需氧型、厭氧型和兼性厭氧型,根據(jù)材料提供信息,氣性壞疽的異化作用類型為厭氧型。(4)本題考查的是細胞的選擇透過性,細胞的功能特性決定于細胞膜上的載體的種類和數(shù)量

【答案】(12分,每空各2分)(1)新陳代謝現(xiàn)象  (2) 代謝產(chǎn)生水   

氨基酸脫水縮合(或有氧呼吸)      (3)  厭氧型

(4)選擇透過性    載體蛋白 

【解析】由反應式:CO2+C5→C32C3學科網(wǎng)(Zxxk.Com)C5+CH2O可知:一定范圍內的CO2增加可以使細胞中C3增加;一定范圍內的光照增強會導致細胞內C5增加。甲圖信息顯示:只考慮光照的影響,光照強度為由n增加到k時,光合速率幾乎不變,而乙圖的變化應是光照之外的其他因素引起,比如溫度等

【答案】(10分,每空各2分)(1)低、高、約等于   (2)溫度   

(3)光照強度、CO2濃度、溫度

31.(20分)【解析】:(1)該6個品系玉米的基因型分別為:①:AABBCCDDEE  ②:aaBBCCDDEE  ③:AAbbccDDEE  ④:AABBCCddEE  ⑤:AABBCCDDee  ⑥:aabbccddee

基因分離定律適用于一對等位基因控制的相對性狀的遺傳,基因自由組合定律適用于2對(及以上)的同源染色體上的2對(及以上)等位基因控制的性狀遺傳。具有兩對相對性狀的純合親本雜交,F(xiàn)1自交。若F2中出現(xiàn)性狀分離比為:雙顯∶單顯1∶單顯2∶雙隱=9∶3∶3∶1,則控制這兩對相對性狀的基因位于2對同源染色體上,反之則位于同一染色體上

讓F1側交,若F2中出現(xiàn)性狀分離比為:雙顯∶單顯1∶單顯2∶雙隱=1∶1∶1∶1,則控制這兩對相對性狀的基因位于2對同源染色體上,反之則位于同一染色體上

【答案】(1)②與①(③或、④、⑤) (1分)  不行  (1分)  品系①和⑤只有一對相對性狀   (2分)不行 (1分)  控制花色和種皮顏色的基因位于同一對同源染色體(Ⅰ)上,而控制子葉味道的基因位置未知(2分)

(2)D(1分)

①若綠色非甜子葉∶綠色甜子葉∶黃色非甜子葉∶黃色甜子葉=9∶3∶3∶1,則控制子葉顏色和味道的基因不是位于同一染色體上。(3分)

②若綠色非甜子葉∶綠色甜子葉∶黃色非甜子葉∶黃色甜子葉≠9∶3∶3∶1(答綠色甜子葉:綠色非甜子葉:黃色非甜子葉=1:2:1也可),則控制子葉顏色和味道的基因位于同一染色體上。(3分)

(3)

①若綠色非甜子葉∶綠色甜子葉∶黃色非甜子葉∶黃色甜子葉=1∶1∶1∶1,則控制子葉顏色和味道的基因不是位于同一染色體上。(3分)

②若綠色非甜子葉∶綠色甜子葉∶黃色非甜子葉∶黃色甜子葉≠1∶1∶1∶1(答綠色甜子葉:黃色非甜子葉=1:1也可),則控制子葉顏色和味道的基因位于同一染色體上。(3分)

 

 

 


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