【題目】為了驗(yàn)證木炭可被濃H2SO4氧化成CO2,選用如圖所示儀器(內(nèi)含物質(zhì))組裝成實(shí)驗(yàn)裝置:
(1)如按氣流由左向右流向,連接上述裝置的正確順序是(填各接口字母):________接________,________接________,________接________。
(2)儀器乙、丙應(yīng)有怎樣的實(shí)驗(yàn)現(xiàn)象才表明已檢驗(yàn)出CO2?
乙中________________________,丙中________________________。
(3)丁中酸性KMnO4溶液的作用是__________________________________________。
(4)寫(xiě)出甲中反應(yīng)的化學(xué)方程式____________________________________________。
【答案】(1)A F E C D B
(2)澄清石灰水變渾濁 品紅溶液未褪色
(3)吸收SO2
(4)C+2H2SO4(濃)CO2↑+2SO2↑+2H2O
【解析】木炭與濃硫酸加熱反應(yīng)生成CO2、SO2和H2O。其中CO2、SO2在化學(xué)性質(zhì)上的相同點(diǎn)都是酸性氧化物,都跟澄清石灰水中的Ca(OH)2反應(yīng),使澄清石灰水變渾濁,這會(huì)干擾CO2的鑒別。SO2和CO2在化學(xué)性質(zhì)上的明顯不同點(diǎn)是SO2有漂白性和強(qiáng)的還原性,而CO2都沒(méi)有。所以,在鑒別CO2時(shí),首先用酸性KMnO4溶液將SO2氧化除去,再用品紅溶液檢驗(yàn)是否被完全除去,最后用澄清石灰水檢驗(yàn)CO2的存在,是一種確認(rèn)CO2存在的好方案。
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